Product ID:37 13F12L IOZ RICH LIQUID, 37-13F12L
MSDS Date:05/22/1995
FSC:8010
NIIN:00N016548
MSDS Number: BZZYB

VALSPAR CORP

1101 THIRD STREET SOUTH
MINNEAPOLIS, MN 55415
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 612-332-7371

Cage: 13418

VALSPAR CORPORATION

MINNEAPOLIS, MN 55415 US

Telephone: 612-332-7371/800-228-5635

Cage: 13418

SILICA, CRYSTALLINE - QUARTZ; (CRYSTALLINE SILICA)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: <1%

OSHA PEL 0.1 MG/M3 (MFR)

ACGIH TLV: 0.1 MG/M3 RDUST

SILICA, CRYSTALLINE - CRISTOBALITE; (SILICA)

CAS: 14464-46-1

RTECS: VV7325000

Fraction By Weight: <1%

OSHA PEL 0.05 MG/M3 (MFR)

ACGIH TLV: 0.05 MG/M3 RDUST

SILICA ACID, ETHYL ESTER; (ETHYL SILICATE)

CAS: 11099-06-2

Fraction By Weight: 50%

OSHA PEL 100 PPM (MFR)

ACGIH TLV: 10 PPM (MFR)

ETHANOL, 2-BUTOXY-; (BUTYL CELLOSOLVE)

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 5%

OSHA PEL 50 PPM, S

ACGIH TLV: 25 PPM, S

2-PROPANOL, 1-METHOXY-; (PROPYLENE GLYCOL MONOMETHYL ETHER)

CAS: 107-98-2

RTECS: UB7700000

Fraction By Weight: 20-30%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM;150 STEL

2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 5-10%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM;300 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SILICATE, MICA; (MICA)

CAS: 12001-26-2

RTECS: VV8760000

Fraction By Weight: 5%

OSHA PEL 20 MPPCF

ACGIH TLV: 3 MG/M3 RDUST

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:CAN BE ABSORBED THRU SKIN.
HARMFUL IF INHALED. MAY AFFECT BRAIN, NERV SYS/RESP SYS, CAUSING
DIZZ, HDCH, NAUS/RESP IRRIT. OVEREXP TO INGS IN THIS PROD MAY CAUSE
NOSE & THROAT IRRIT, EYE/SKIN IRRI T, LIVER/KIDNEY DMG, RESP TRACT
IRRIT. CHRONIC:CONTAINS GLYCOL ETHER WHICH HAS BEEN SHOWN TO CAUSE
BLOOD EFTS DMG IN LAB ANIMALS. PRLNG EXPOS TO RESPIRABLE
CRYSTALLINE QUARTZ (SILICA) MAY CAUSE DELAYE D (CHRONIC) LUNG
INJURY (SILICOSIS). PRLNG EXPOS OVER TLV MAY PRODCE PNEUMOCONIOSIS.
NOTICE:RPTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP TO SOLVS W/PERM
BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ &
CRISTOBALITE:IARC MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GRP 2A. NTP
7TH ANNUAL RPT ON CARCIN, 1994:ANTIC TO BE CARCIN.
Effects of Overexposure:HLTH HAZ:CONCENTRATING & INHALING CONTENTS MAY
BE HARMFUL/FATAL. CONTAINS INGS WHICH MAY CAUSE LIVER/KIDNEY DMG.
WARNING! THIS PROD CONTAINS CHEMS KNOWN TO STATE OF CALIFORNIA TO
CAUSE CANCER & TO CAU SE BIRTH DEFECTS/OTHER REPRO HARM. ANIMAL
STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS,
HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER, ASSOC W/ADMIN OF
ETHYLENE GLYCOL MONOBUTYL ETHER (E GBE). (EXTRACTED FROM DHHS
(NIOSH) PUBLICATION NO.90-118) .
Medical Cond Aggravated by Exposure:ANY RESPIRATORY OR SKIN CONDITION.

First Aid:EYES:FLUSH IMMED W/PLENTY OF WATER FOR AT LST 15 MINS & GET
MED ATTN. SKIN:WASH THORO W/SOAP & WATER. REMOVE CONTAM CLTHG &
SHOES. WASH CLTHG BEFORE REUSE. THORO CLEAN CONTAM SHOES.
INHAL:REMOVE TO FR ESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG
IS DFCLT, GIVE OXYG. GET MED ATTN IMMED. INGEST:DO NOT INDUCE
VOMIT. GIVE LG QTYS OF WATER. IF AVAIL, GIVE SEVERAL GLASSES OF
MILK. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET
MEDICAL ATTENTION IMMEDIATELY.

Flash Point Method:TCC
Flash Point:69.0F,20.6C
Lower Limits:1%
Upper Limits:16%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM &/OR WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . CONTAINERS EXPOSED TO FIRE SHOULD BE KEPT COOL W/WATER
SPRAY.
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:VENTILATE AREA. AVOID BREATHING OF VAPORS. USE
NIOSH/MSHA APPROVED SCBA OR AIRMASK FOR LARGE SPILLS IN A CONFINED
AREA. ELIMINATE IGNITION SOURCES. REMOVE W/INERT ABSORBENT &
NON-SPARKING TOOLS. AVOID CONTACT W/EYES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CNTNRS SHOULD BE GROUNDED/BONDED WHEN
POURING. AVOID FREE FALL OF LIQ IN EXCESS OF A FEW INCHES. KEEP
AWAY FROM HEAT, SPARKS & OPEN FLAMES.
Other Precautions:KEEP CNTNR CLSD WHEN NOT IN USE. DO NOT STORE >120F.
BASED ON PROD FLASH POINT & VAP PRESS SUITABLE STOR SHOULD BE
PROVIDED I/A/W OSHA REG 1910.106. EMPTY CNTNRS MAY CONTAIN PROD
RESIDUE, INCL FLAMM/E XPLO VAPS. DO NOT CUT, PUNCTURE/WELD ON OR
NEAR CONTAINER. ALL LABEL WARNINGS MUST BE OBSERVED UNTIL CNTNR
HAS (SUP DAT)

Respiratory Protection:UNLESS AIR MONITORING DEMONSTRATES VAP/MIST
LEVELS ABOVE APPLIC LIMS, NO RESP IS REQD. IF RESP IS REQD, APPROP,
PROPERLY FITTED NIOSH/MSHA APPRVD RESP SHOULD BE WORN DURING
APPLICATION. FOLLOW RESP MF R'S DIRECTIONS FOR RESPIRATOR USE.
Ventilation:REQUIRED FOR SPRAYING OR IN CONFINED AREA, VENT EQUIPMENT
SHOULD BE EXPLOSION PROOF. ELIMINATE IGNITION SOURCES.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . USUAL CLOTHING FOR PAINTING OPERATIONS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
OTHER PREC: BEEN CLEANED/RECONDITIONED.

Boiling Pt:B.P. Text:156F,69C
Vapor Pres:78 @ 68F
Vapor Density:4.1
Spec Gravity:1.1
Evaporation Rate & Reference:5.6 (BUTYL ACETATE=1)
Solubility in Water:NO
Appearance and Odor:NORMAL FOR A COATINGS PRODUCT.
Percent Volatiles by Volume:41.25

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:SILICON DIOXIDE, NITROGEN OXIDES,
CARBON DIOXIDE/MONOXIDE, METAL OXIDES.

Waste Disposal Methods:DISPOSE IN CHEMICAL DISPOSAL AREA OR IN A MANNER
THAT COMPLIES W/LOCAL, STATE & FEDERAL REGULATIONS. DO NOT
INCINERATE CLOSED CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.